Optical library system consists of disc magazines, cabinets, transfer robot and drive. Transfer robot delivers desired disc or magazine in cabinet to drive which reads data of disc. Conventional archive system stores discs in a line and transfer robot moves in one dimension. However, to store more discs, new optical archive system, optical library system, is developed which stores discs in two dimension like bookcase. Transfer robot should know the position and stored data of desired magazine to get correct data. In this paper, addressing algorithm using optical character recognition is proposed. Proposed algorithm is evaluated by experiments with implemented system.